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A Feasibility Study on HPMC-Improved Sulphoaluminate Cement for 3D Printing

A Feasibility Study on HPMC-Improved Sulphoaluminate Cement for 3D Printing

A Feasibility Study on HPMC-Improved Sulphoaluminate Cement for 3D Printing

A novel 3D printing material based on hydroxypropyl methylcellulose (HPMC)—improved sulphoaluminate cement (SAC) for rapid 3D construction printing application is reported. The hydration heat, setting time, fluidity of paste and mortar, shape retainability, and compressive strength of extruded SAC mortar were investigated. HPMC dosage, water-to-cement (W/C) ratio, and sand-to-cement (S/C) ratio were studied as the experimental parameters. Hydration heat results reveal HPMC could delay the hydration of SAC. The initial and final setting time measured using Vicat needle would be shortened in the case of W/C ratio of 0.3 and 0.35 with HPMC dosage from 0.5% to 1.5%, W/C ratio of 0.40 with HPMC dosage of 0.5%, 0.75%, and 1.5%, and W/C ratio of 0.45 with HPMC dosage of 0.45, or be extended in the case of W/C ratio of 0.4 with HPMC dosage of 1.0% and W/C ratio of 0.45 with HPMC dosage from 0.75% to 1.5%. Fluidity measurement shows HPMC significantly improves the shape retainability. Furthermore, the addition of HPMC remarkably increased the compressive strength of extruded mortar. The results showed that HPMC could be used to prepare 3D printing SAC having satisfactory shape retainability,

setting time and compressive strength.

Materials 11 02415 g007 550Representative pictures during measuring fluidity of paste: (a) a mold filled with paste; (b) control paste with W/C of 0.3 after removing a mold.

 Influence of W/C Ratio and HPMC Content on the Fluidity of the SAC Paste

The lower mouth diameter of the truncated conical mold used for the fluidity test was 60 mm (Figure 7a). Thus, the test results of 60 mm fluidity showed that the pastes did not flow away after removing the mold (Figure 7b). Lower W/C ratio could result in lower paste fluidity, irrespective of the presence or absence of HPMC, because lower W/C ratio indicates smaller space and shorter distance between particles in fresh paste (Figure 4), forming greater interparticle friction. The friction is the key factor that affects fluidity. As a result, the lower the W/C ratio, the lower the fluidity. When the W/C ratio of the control paste is 0.30, the friction between the particles is high enough to withstand the flow of paste.

Link: https://www.mdpi.com/1996-1944/11/12/2415/htm

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